It sounds like you are using a scheduled backup.
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Originally Posted by SD! User's Guide
Note
Other than the date/time, or temporarily disabling an individual item, your backups cannot (currently) be changed once scheduled. If you want to change the volumes or options, you’ll have to delete and recreate the entry.
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All of the settings for a scheduled backup are saved when that backup is scheduled. Later changes made to the settings (source, destination, "copy script", and the "Options…") do not affect backups that are already scheduled.
The usual way to change (e.g.) the "On successful completion" setting of an already scheduled backup would be to reconfigure the main window to have the settings you want (i.e. re-create the settings of the already scheduled backup, but including the changes you want). Then Schedule… this new backup with the same schedule settings (dates, times, etc.) as the old one. Then delete or disable the old one.