Most things aren't there because they're "too difficult", but rather because I'm pretty ruthlessly focused on keeping things as simple as possible...
What you can do is, if you're going to schedule something, save the setup first with File > Save. Then, you can schedule it, and also run when you'd like.
Alternatively, you can open the settings in Library/Application Support/SuperDuper!/Scheduled Copies and run them...
Hope that helps.
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--Dave Nanian
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