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The error message is "Permission denied", so you can probably fix it with chmod a+rx /Volumes/HomeDrive/Users/gina/Library/Application Support/SuperDuper!/Shell Scripts/superduper_mountdisk.sh (give "everyone" read and execute permission).
But if all you want is to mount a volume before a backup and unmount the volume afterwards, I think SuperDuper! can already do what you want by itself (no scripts needed). See the Note on p40 at the end of the “Saving and restoring settings” section of the User's Guide (accessible via the Help menu)).
If the target (or source) volume for a saved settings file (for example a scheduled backup, or the default saved settings) is not mounted, SuperDuper! will try to mount it automatically. All you have to do is just unmount your target volume sometime before the next backup. The next time SuperDuper! loads the settings file that targets the volume, SuperDuper! will mount it automatically. For scheduled backups, I think it also automatically unmounts the volume iff it was automatically mounted (though the only mentions of unmount in the User's Guide refer to disk images (either local or on a network share)).
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